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Electron probe micro-analyzer (EPMA) CAMECA SX-100
Instrument
The electron probe micro-analyzer (EPMA), also known as microprobe, is a non-destructive method used to determine the chemical composition of solid samples. EPMA works by bombarding a micro-volume of a sample with a focused electron beam (typical energy = 5-30 keV) and collecting the X-ray photons thereby emitted by the various elemental species. Because the wavelengths of these X-rays are characteristic of the emitting species, the sample composition is determined by recording WDS spectra (Wavelength Dispersive Spectroscopy). The primary importance of an EPMA is the ability to acquire precise, quantitative elemental analyses (as low as 50 ppm) of the majority of the elements (from boron to plutonium) of a complex sample of very small spot sizes (1-2 µm). The spatial scale of analysis, combined with the ability to create detailed images of the sample, makes it possible to analyze a multitude of solid samples such as rocks and minerals, metals and alloys, glass, optical fibers, ceramics, semiconductor materials, concrete, cement. The electron microprobe is an automated instrument, enabling analysis, profiling or elemental mapping of solid samples.

CAMECA SX-100
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Applications
Rutile is a source of titanium, particularly for the production of products such as titanium dioxide pigments (TiO2) and titanium (metal). It is a common mineral found in copper porphyry, and its TiO2 content is generally high (95%), the remainder being made up of several other metals, including Fe, Cr, V, Sn, Nb and Ta. Due to its morphology and geochemistry, rutile are recognized as a potential indicator mineral for exploration.
In this publication, Geochemistry of hydrothermal and stream sedimentary rutile in the Tiegelongnan porphyry-epithermal Cu (Au) deposit, Tibet: A tool for exploration (Yang et al., Ore Geology Reviews, 2024, 167, 105970), the researchers used the electron microprobe microanalyzer (EPMA) to characterize the physical properties and chemical composition of hydrothermal rutile and data proved the capability of using rutile as a proxy mineral for the exploration of porphyry copper deposits.

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Sample preparation
Samples should be perfectly flat, ideally in the form of polished sections or thin slides to allow flawless electron-sample interactions. Smooth surfaces are of paramount importance for samples containing minerals with different hardness. For electrical insulator samples (like most silicates), directing an electron beam at the sample can lead to electrical charging of the sample, which must be dissipated. Insulating are typically coated with a thin film of a conducting material. The microprobe sample holder accepts circular sections (25 and 30mm diameter) or standard 25mm petrographic slides.