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X-ray photoelectron spectroscopy (XPS) KRATOS Analytical AxisUltra

Instrument

X-ray photoelectron spectroscopy (XPS) is a non-destructive analytical technique in which x-rays bombard the surface of a material and the kinetic energy of the emitted electrons is measured. It is widely used to characterize the surfaces of various materials (inorganic compounds, organics, semiconductors, natural materials (lignocellulose) and synthetics (meso- and microporous ceramics). This technique analyzes the outer layer of materials (1 to 10 nm; 30 atomic layers) and allows the characterization of: 1) the chemical composition of material surfaces (element identification); 2) the relative abundance of these components on surfaces (semi-quantitative analysis) and; 3) the oxidation state of surface elements (precision depending on the quantity and complexity of the sample). All elements of the periodic table (Li to U) are detectable, with the exception of hydrogen and helium.

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KRATOS Analytical Axis-Ultra

Rates

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Applications​

There is an increasing trend towards treatment of refractory sulphidic gold ores as a result of rarefaction of free-milling gold ores. In this publication The effect of flotation collectors on the electrochemical dissolution of gold during cyanidation (A. D. Bas, F. Larachi, Miner. Eng. 2019, 130, 48), the researchers confirmed by XPS measurement leach residue of gold (Au). Depending on the process used, the presence of several spectral lines confirms that the gold in the residue was surrounded by pyrite (FeS2) particles when the mixture of gold (Au) and pyrite (FeS2) was conditioned with the collector (sodium-diisobutyl dithiophosphinate; Aerophine 3418A; spectral lines Na, O, C and S) prior to cyanidation.


Contact

Contact

Yi Dong, PhD


Tél: 418 656-2131 poste 412736

Courriel: microlab-xps@fsg.ulaval.ca

Booking

Sample preparation

Samples used for XPS analyses are used “as is”, as any chemical treatment can leaves contaminating residues. Samples must be stable under ultra-high vacuum (< 10-9 Torr).
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